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Looks to me like Daphne's a ginger and Velma's a brunette. Also, they do both seem to be fairly well blessed. Also, I don't remember this scene from Scooby Doo episodes when I was growing up.
I think the confusion everyone is having is that Bree Olson plays Daphne in the porn parody and she's blonde, so it's throwing all of you guys off.